ChemInform Abstract: PURINES. XXII. METHYLATION OF 1-, 3-, 7-, 9-, AND N6-METHYLADENINES BEARING A A METHOXYL GROUP AT THE N6-POSITION: A SYNTHESIS OF 7,9-DIMETHYLADENINE

Autor:	Tsuyoshi Nakasaka, Taisuke Itaya, Fumiko Tanaka, Kiyomi Yamamoto, Tohru Saito, Tozo Fujii, Kazuyo Mohri
Rok vydání:	1984
Předmět:	Perchlorate chemistry.chemical_compound chemistry Pyrimidine Group (periodic table) Stereochemistry Dimethyladenine Regioselectivity Imidazole Moiety General Medicine Methylation
Zdroj:	Chemischer Informationsdienst. 15
ISSN:	0009-2975
DOI:	10.1002/chin.198410192
Popis:	The effect of the N6-methoxy group on regioselectivity in methylation of all five possible isomers of N-methyladenine has been investigated. The methoxyl group attached to all these isomers orients methylation to a considerable extent to nitrogen(s) in the same pyrimidine or imidazole moiety that the original N-methyl group is attached to. On the basis of the results of the present methylation study, 7,9-dimethyladeninium perchlorate has been synthesized from 7- or 9-methyl-N6-methoxyadenine.
Databáze:	OpenAIRE
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