Synthesis of complex polymeric architectures using multilithiated carbanionic initiators—Comparison with other approaches

Autor:	Yves Gnanou, Rachid Matmour
Rok vydání:	2013
Předmět:	Materials science Polymers and Plastics Organic Chemistry Surfaces and Interfaces Combinatorial chemistry chemistry.chemical_compound Monomer Star polymer chemistry Polymerization Polymer chemistry Materials Chemistry Ceramics and Composites Macromolecule
Zdroj:	Progress in Polymer Science. 38:30-62
ISSN:	0079-6700
DOI:	10.1016/j.progpolymsci.2012.08.003
Popis:	This article reviews the various methods developed to generate di- and multicarbanionic lithiated initiators, the difficulties associated with their synthesis but also their potential in macromolecular engineering. It is shown that a wealth of complex macromolecular architectures based on monomers amenable to carbanionic polymerization can now be synthesized by divergent approach from these di- and multicarbanionic lithiated initiators. A comparison is made with other types of multifunctional initiators that have been developed from other living/controlled polymerizations, generating similar complex polymeric architectures from other monomers. A comparison is also made with the structures generated by the convergent carbanionic approach.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9c1d1a966a31b664e218ee965870b139 https://doi.org/10.1016/j.progpolymsci.2012.08.003 Zobrazit plný text záznamu Full Text from ScienceDirect