Study of Dithienylcyclopentene with Substituents at 4-Position of Thiophene

Autor: Sheng Min Zhao, Wen Guan Zhang, Wei Lin Zhang, Han Hui Huang
Rok vydání: 2014
Předmět:
Zdroj: Advanced Materials Research. :1105-1108
ISSN: 1662-8985
DOI: 10.4028/www.scientific.net/amr.1033-1034.1105
Popis: 1-(2,5-Dimethylthien-3-yl)-2-(4-acetyl-2,5-dimethylthien-3-yl) cyclopentene has been synthesized by a six-step procedure, such as Vilsmeier reaction, Wolff-Kishner-Huang reduction reaction, The Friedel-Crafts acylation, McMurry reaction etc. Upon alternate irradiation with 297 and 500 nm light upon 1-(2,5-Dimethylthien-3-yl)-2-(4-acetyl-2,5-dimethylthien-3-yl) cyclopentene, the absorption spectrum changes reversibly and a clear isosbestic point appears. These results suggest that the compound can undergo photochromism and do not decompose during the irradiation.
Databáze: OpenAIRE