Degree and Influence of MoS··S Interactions in Oxo−Molybdenum(VI,V,IV) Complexes

Autor:	Charles G. Young, Robert W. Gable, Jason P. Hill, Les J. Laughlin
Rok vydání:	1996
Předmět:	Inorganic Chemistry Degree (graph theory) chemistry Molybdenum chemistry.chemical_element Physical and Theoretical Chemistry Boron Redox Medicinal chemistry
Zdroj:	Inorganic Chemistry. 35:3447-3448
ISSN:	1520-510X 0020-1669
Popis:	This paper draws a contrast between the molecular and electronic structures of the oxo−thio−Mo(VI) complex LMoVIOS(S2PPr2-S) and the dithio−oxo−Mo(IV) complex LMoIVO(pyS2-N,S) [pyS2 = pyridyl-2-dithio; L = hydrotris(3,5-dimethylpyrazol-1-yl)borate] and reports the generation of Mo(V) species by the reduction or oxidation of these (formally) Mo(VI) and Mo(IV) complexesa spectacular demonstration of the redox versatility of Mo−S centers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9be7c2e0858a5c23374b97ed0e951108 https://doi.org/10.1021/ic951645g Zobrazit plný text záznamu