Manganese-Catalyzed Synthesis of Imines from Primary Alcohols and (Hetero)Aromatic Amines

Autor: M. Manuel B. Marques, Beatriz Royo, Sofia Friães, Daniel Raydan, Nuno Viduedo, A. Sofia Santos, Clara S. B. Gomes
Rok vydání: 2022
Předmět:
Zdroj: Synlett. 33:1290-1294
ISSN: 1437-2096
0936-5214
DOI: 10.1055/a-1828-1678
Popis: Herein, we describe the synthesis of a wide variety of imines through oxidative coupling of alcohols and aromatic amines catalyzed by Mn complexes bearing N^N triazole ligands. A wide variety of imines in excellent yields (up to 99%) have been prepared. Mn-based catalysts proved to be highly efficient and versatile, allowing for the first time the preparation of several imines containing N-based heterocycles.
Databáze: OpenAIRE