Manganese-Catalyzed Synthesis of Imines from Primary Alcohols and (Hetero)Aromatic Amines
Autor: | M. Manuel B. Marques, Beatriz Royo, Sofia Friães, Daniel Raydan, Nuno Viduedo, A. Sofia Santos, Clara S. B. Gomes |
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Rok vydání: | 2022 |
Předmět: | |
Zdroj: | Synlett. 33:1290-1294 |
ISSN: | 1437-2096 0936-5214 |
DOI: | 10.1055/a-1828-1678 |
Popis: | Herein, we describe the synthesis of a wide variety of imines through oxidative coupling of alcohols and aromatic amines catalyzed by Mn complexes bearing N^N triazole ligands. A wide variety of imines in excellent yields (up to 99%) have been prepared. Mn-based catalysts proved to be highly efficient and versatile, allowing for the first time the preparation of several imines containing N-based heterocycles. |
Databáze: | OpenAIRE |
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