Selective transformations of phenylated diynes to polycyclic compounds by the RhCl3- and PtCl4-Aliquat 336® ion pair catalysts

Autor:	Waël Baidossi, Herbert Schumann, Jochanan Blum
Rok vydání:	1996
Předmět:	Organic Chemistry Intermolecular force Ion pairs Aliquat 336 Biochemistry Chloride Catalysis chemistry.chemical_compound chemistry Phase (matter) Drug Discovery Polymer chemistry medicine medicine.drug
Zdroj:	Tetrahedron. 52:8349-8364
ISSN:	0040-4020
DOI:	10.1016/0040-4020(96)00394-8
Popis:	The ion pairs generated from methyltricaprylammonium chloride and either RhCl 3 or PtCl 4 catalyze, under phase transfer conditions, selective cyclore-arrangements, as well as intra- and intermolecular addition processes by which discrete polycyclic compounds are formed. The nature of the products depends on the distances between the ethynyl functions and on the catalyst employed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9bd9570f121de1ac9710fe25ed3cb4cc https://doi.org/10.1016/0040-4020(96)00394-8 Zobrazit plný text záznamu Full Text from ScienceDirect