Aerobic catalytic epoxidation of unfunctionalized olefins using a new (salen)manganese (III) complex bearing a sesquiterpene salicylaldehyde derivative

Autor:	J. R. Pedro, Isabel Fernández, Roberto de la Salud
Rok vydání:	1996
Předmět:	Organic Chemistry chemistry.chemical_element Manganese Sesquiterpene Biochemistry Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Salicylaldehyde Yield (chemistry) Drug Discovery Organic chemistry Molecular oxygen Enantiomeric excess Derivative (chemistry)
Zdroj:	Tetrahedron. 52:12031-12038
ISSN:	0040-4020
DOI:	10.1016/0040-4020(96)00697-7
Popis:	A chiral (salen) manganese (III) complex 1 bearing a sesquiterpene salicylaldehyde and ( R , R )-1,2-cyclohexanediamine moieties has been prepared. This complex catalyses the epoxidation of unfunctionalized olefins with iodosylbenzene and molecular oxygen/pivalaldehyde as terminal oxidants. In all cases the chemical yield was high although the enantiomeric excess obtained were low.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9bd00d26cd979b038439dff64bbeadc1 https://doi.org/10.1016/0040-4020(96)00697-7 Zobrazit plný text záznamu Full Text from ScienceDirect