Structure-performance relationship of Mg(OEt)2-based Ziegler-Natta catalysts
| Autor: | Toru Wada, Ashutosh Thakur, Minoru Terano, Toshiaki Taniike, Toshiki Funako, Patchanee Chammingkwan, Akanksha Matta |
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| Rok vydání: | 2020 |
| Předmět: |
Pairwise correlation
biology 010405 organic chemistry Chemistry Natta 010402 general chemistry biology.organism_classification 01 natural sciences Catalysis 0104 chemical sciences Chemical engineering Ethylene polymerization Olefin polymerization Particle Particle size Physical and Theoretical Chemistry |
| Zdroj: | Journal of Catalysis. 389:525-532 |
| ISSN: | 0021-9517 |
| Popis: | A multivariate aspect has hampered the clarification of structure-performance relationships in heterogeneous Ziegler-Natta olefin polymerization catalysis. Here, 16 catalyst samples were prepared using Mg(OEt)2 support precursors with different particle architectures. They were fingerprinted based on a series of characterization and analytical methods. In a pairwise correlation analysis, none of structural features (such as particle size and pore volume) exhibited a clear correlation with ethylene polymerization performance. However, compound features created among different structural features reasonably reproduced the ethylene polymerization activity as well as 1-hexene incorporation efficiency, where a negative influence of pores with the size below 10 nm was dictated. |
| Databáze: | OpenAIRE |
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