Reactions of phenyltellurium(VI) fluorides with alcohols, amines and silicon compounds

Autor:	Alexander F. Jansen, K. Alam, Barry J. Blackburn
Rok vydání:	1989
Předmět:	Inorganic Chemistry NMR spectra database chemistry.chemical_compound Trimethylsilyl chemistry Silicon Organic Chemistry Environmental Chemistry chemistry.chemical_element Organic chemistry Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Fluorine Chemistry. 42:173-178
ISSN:	0022-1139
DOI:	10.1016/s0022-1139(00)82747-5
Popis:	The reactions of phenyltellurium(VI) fluorides, PhTeF 5 , trans -Ph 2 TeF 4 and mer -Ph 3 TeF 3 , with alcohols and amines, or their trimethylsilyl derivatives, are described. The products PhTeF 4 X, Ph 2 TeF 3 X and Ph 3 TeF 2 X (X=OMe, NMe 2 , NEt 2 were characterized by 19 F NMR and isomeric structures are assigned on the basis of their NMR spectra. Samples of trans -Ph 2 TeF 4 contain small amounts of cis -Ph 2 TeF 4 .
Databáze:	OpenAIRE
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