Absolute Konfiguration der Equisetumalkaloide (+)-Palustrin, Palustridin ((+)-Monohydrochlorid) sowie der (−)-Dihydropalustraminsäure und weiterer Derivate. 16. Mitteilung über Schachtelhalmalkaloide

Autor:	Peter Christian Wälchli, Conrad Hans Eugster, Gabriele Mukherjee-Müller
Rok vydání:	1978
Předmět:	Inorganic Chemistry Chemistry Stereochemistry Organic Chemistry Drug Discovery Absolute configuration Physical and Theoretical Chemistry Biochemistry Catalysis
Zdroj:	Helvetica Chimica Acta. 61:921-928
ISSN:	0018-019X
DOI:	10.1002/hlca.19780610239
Popis:	Determination of the absolute configuration of alkaloids from Equisetum sp.,e.g. (+)-palustrin, palustridin ((+)-hydrochloride), and (−)-dihydropalustramic acid and derivatives The absolute configuration of the title alkaloids has been determined using chiroptical methods (ORD., superposition of CD. values of appropriate models and a modified Horeau method). (+)-Palustrin is (13R, 17 S, 1′S)-17-(1-hydroxypropyl)-1,5,10-triazabicyclo [11.4.0]heptadec-15-en-11-on.
Databáze:	OpenAIRE
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