Preparation of a Monochiral Terpenoid SynthonfFrom Carvone Using a Stereoselective Intramolecular Nitrile Oxide Cycloaddition

Autor:	J.-P. Gesson, S. A. M. Nieuwenhuis, B. Renoux
Rok vydání:	1993
Předmět:	chemistry.chemical_compound Stereospecificity chemistry Nitrile Bicyclic molecule Stereochemistry Synthon Nitro Molecular Medicine Organic chemistry Stereoselectivity Oxime Cycloaddition
Zdroj:	Natural Product Letters. 2:129-135
ISSN:	1057-5634
DOI:	10.1080/10575639308043797
Popis:	Starting from (-)-carvone, two consecutive regio- and stereospecific alkylations followed by a stereoselective INOC reaction, carried out either on a nitro derivative or on the corresponding oxime, afford, in few overall steps, a monochiral bicyclic synthon which may be used for the preparation of terpenes such as aphidicolin.
Databáze:	OpenAIRE
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