ChemInform Abstract: Unusual Cyclopropanol Formation from a β-Silyl Aldehyde

Autor:	Ian N. Fleming, Ajay K. Mandal
Rok vydání:	2010
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Silylation Chemistry Group (periodic table) Cyclopropanol Oxyanion General Medicine Medicinal chemistry Aldehyde
Zdroj:	ChemInform. 30
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199937073
Popis:	The hemiacetals 15 and 18 gave cyclopropanols 17 and 20 when treated with NaH in DMSO, showing that the silyl group has enhanced electrofugal powers because of the participation of the oxyanion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b79d2999d219dbd82f84a3ae1080e44 https://doi.org/10.1002/chin.199937073 Zobrazit plný text záznamu Plný text