Thladiantha Seed Oils - New Source of Conjugated Fatty Acids: Characterization of Triacylglycerols and Fatty Acids
Autor: | Vu Thi Ngoc Anh, Kovalchukova Olga, Deineka Victor, Doan Thi Lan Phuong, Deineka Ludmina, Nguyen Van Anh |
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Rok vydání: | 2020 |
Předmět: |
chemistry.chemical_classification
0303 health sciences Punicic acid Chromatography biology 030309 nutrition & dietetics Thladiantha dubia General Chemical Engineering 04 agricultural and veterinary sciences General Medicine General Chemistry Carbon-13 NMR Conjugated system biology.organism_classification 040401 food science 03 medical and health sciences Hydrolysis chemistry.chemical_compound 0404 agricultural biotechnology chemistry Mole Urea Polyunsaturated fatty acid |
Zdroj: | Journal of Oleo Science. 69:993-1000 |
ISSN: | 1347-3352 1345-8957 |
DOI: | 10.5650/jos.ess20075 |
Popis: | In this study, seed oils of Thladiantha nudiflora and Thladiantha dubia were found to contain 55.5 and 44.4% mole of conjugated octadecatrienoic fatty acids, respectively. The presence of moieties of conjugated fatty acids was confirmed by a series from physical methods: UV, IR, 1H and 13C NMR. The triacylglycerols (TAGs) isolated of the seed oils were studied by RP-HPLC with diode array and mass spectrometric detections. It was shown that all 15 TAGs of Thladiantha dubia contain moieties of conjugated fatty acids - punicic, (9Z,11E,13Z)-octadeca-9,11,13-trienoic acid (35.6% mole) and 8.9% mole α-eleostearic, (9Z,11E,13E)-octadeca-9,11,13-trienoic acid. Meanwhile, 24 TAGs of Thladiantha nudiflora seed oil contain both acids in approximately equal proportions (27.4:28.2 % mole). The enrichment for polyunsaturated fatty acids of the hydrolysis product of the seed oils due to urea inclusion complex formation was discussed. |
Databáze: | OpenAIRE |
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