Stereoelectronic effects on arene rotation: the structure and fluxionality of [1,4-C6H4(SiMe3)2]Cr(CO)2PPh3 and [1,3,5-C6H3tBu3)Cr(CO)2PPh3

Autor:	Claire J. Beddows, Hugo E. Gottlieb, Desmond Cunningham, Patrick McArdle, Paul C. Yates, Paula J. O'Leary, James A. S. Howell
Rok vydání:	1997
Předmět:	Inorganic Chemistry Chromium Crystallography chemistry Organic Chemistry Materials Chemistry chemistry.chemical_element Crystal structure Physical and Theoretical Chemistry Rotation Ring (chemistry) Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 527:21-27
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(96)06537-0
Popis:	Barriers to metal-arene ring rotation in [1,4-C6H4(SiMe3)2)Cr(CO)2PPh3 and (1,3,5-C6H3tBu2)Cr(CO)2PPh3 are lowered relative to a previously reported barrier of 32 J mol−1 for (1,4-C6H4tBu2)Cr(CO)2PPh3. Reasons for the decreased barriers are discussed in the light of crystal structure determinations of these complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b54ba016daa51e480bba04edfa677e8 https://doi.org/10.1016/s0022-328x(96)06537-0 Zobrazit plný text záznamu Full Text from ScienceDirect