Non-ideal kinetics in free-radical polymerisation
Autor: | D. G. Smith |
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Rok vydání: | 2007 |
Předmět: | |
Zdroj: | Journal of Applied Chemistry. 17:339-343 |
ISSN: | 1934-998X 0021-8871 |
Popis: | The reasons for polymerisation rates not conforming to mathematically predicted relationships are reviewed. Such non-ideal kinetics may result from one or more of the following causes: invalid basic assumptions, degradative transfer, effect of monomer concentration on rate of initiation, diffusion control of termination, and formation of electron-donor/acceptor complexes. Details of the characteristics of each effect are given. |
Databáze: | OpenAIRE |
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