Non-ideal kinetics in free-radical polymerisation

Autor: D. G. Smith
Rok vydání: 2007
Předmět:
Zdroj: Journal of Applied Chemistry. 17:339-343
ISSN: 1934-998X
0021-8871
Popis: The reasons for polymerisation rates not conforming to mathematically predicted relationships are reviewed. Such non-ideal kinetics may result from one or more of the following causes: invalid basic assumptions, degradative transfer, effect of monomer concentration on rate of initiation, diffusion control of termination, and formation of electron-donor/acceptor complexes. Details of the characteristics of each effect are given.
Databáze: OpenAIRE