Synthesis and crystal structures of the heptafluoroacetylacetonatocopper(ii) and 4-iminoheptafluoropent-2-ene-2-aminatocopper(ii) complexes with triphenylphosphine oxide and pyridine

Autor:	Pavel A. Slepukhin, T. I. Filyakova, O. N. Chupakhin, Viktor I. Saloutin, L. V. Saloutina
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Chemistry Yield (chemistry) Polymer chemistry Pyridine chemistry.chemical_element Chelation General Chemistry Crystal structure Photochemistry Copper Ene reaction Triphenylphosphine oxide
Zdroj:	Russian Chemical Bulletin. 58:1132-1138
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-009-0147-7
Popis:	New chelate heptafluoroacetylacetonatocopper(ii) complexes with triphenylphosphine oxide and pyridine as well as the 4-iminoheptafluoropent-2-ene-2-aminatocopper(ii) complex with triphenylphosphine oxide were synthesized. The molecular and crystal structures of the complexes were studied by X-ray diffraction analysis. The reaction of 2-amino-4-imino-heptafluoropent-2-ene with CuO affords bis(4-imino-1,1,1,3,5,5,5-heptafluoropent-2-ene-2-aminato)copper(ii) in ∼90% yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b433ee2796b477cc2d101854f811678 https://doi.org/10.1007/s11172-009-0147-7 Zobrazit plný text záznamu Full text from SpringerLink