Separation of faradaic and capacitive current regions in the redox transformation of poly(3-methylthiophene) with the exclusion of overoxidation processes

Autor:	Mihaly Novak, Cs. Visy, A. Szucs, M. Lakatos
Rok vydání:	1997
Předmět:	Chemistry General Chemical Engineering Capacitive sensing Inorganic chemistry Photochemistry Electrochemistry Capacitance Redox Anode Nitrobenzene chemistry.chemical_compound Electrode Redistribution (chemistry)
Zdroj:	Electrochimica Acta. 42:651-657
ISSN:	0013-4686
DOI:	10.1016/s0013-4686(96)00210-1
Popis:	The electrostability of the poly(3-methylthiophene) film prepared in nitrobenzene provided the opportunity to study its redox transformations in an extended anodic potential region with the exclusion of the overoxidation. From spectroelectrochemical results a capacitive region could be separated in the highly oxidized state of the layer which exhibited a large capacitance. This pattern—assumed to be related to charge separation/redistribution within the film at high potential field connected to solvent movements—is promising from the point of view of symmetric p-type/n-type superconductors.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b4252cac2ef20163a10f4d3d4bd4b94 https://doi.org/10.1016/s0013-4686(96)00210-1 Zobrazit plný text záznamu Full Text from ScienceDirect