Chemical reactions in the Mo-W-Al2O3 system at 2400 K and 100 Pa

Autor:	Kh. S. Bagdasarov, D. V. Kostomarov, V. A. Fedorov
Rok vydání:	2012
Předmět:	Inorganic Chemistry Chemistry Molar ratio General Chemical Engineering Environmental chemistry Inorganic chemistry Materials Chemistry Metals and Alloys Composition (visual arts) Direct reaction Chemical reaction
Zdroj:	Inorganic Materials. 48:145-149
ISSN:	1608-3172 0020-1685
DOI:	10.1134/s0020168512010086
Popis:	We examine the behavior of the Mo-W-Al2O3 system at T = 2400 K and p = 100 Pa and identify the main chemical reactions that lead to the oxidation of Mo and W. The results indicate that, under these thermodynamic conditions, direct reaction between Mo, W, and molten Al2O3 is impossible, and oxidation processes are indirect and involve vapor species. For a Mo: W: Al2O3 molar ratio of 1: 1: 1, we calculate the gas-phase composition and demonstrate that the predominant vapor species are Al, AlO, Al2O, MoO, MoO2, and WO3.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b0fb3260375f01912e69930681c84b8 https://doi.org/10.1134/s0020168512010086 Zobrazit plný text záznamu Plný text ve formátu PDF