Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

Autor:	Margarita R. Geraskina, Akira Yoshimura, Cumali Çelik, Victor N. Nemykin, Viktor V. Zhdankin, Mekhman S. Yusubov
Rok vydání:	2014
Předmět:	Anthracene Adamantane Organic Chemistry Photochemistry Biochemistry Toluene Catalysis chemistry.chemical_compound chemistry Catalytic oxidation Drug Discovery Polymer chemistry Phthalocyanine Stoichiometry Naphthalene
Zdroj:	Tetrahedron Letters. 55:5687-5690
ISSN:	0040-4039
Popis:	Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5 and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9afffa41628dd3617e8d45051bd56302 https://doi.org/10.1016/j.tetlet.2014.08.070 Zobrazit plný text záznamu Full Text from ScienceDirect