X-ray powder diffraction characterization of Bi14(Sr,Ca)12O33 solid solutions

Autor:	F. Jiang, Winnie Wong-Ng, Bryan R. Jarabek, Gregory J. McCarthy
Rok vydání:	1996
Předmět:	Radiation Materials science Degree (graph theory) Neutron diffraction Center (category theory) Crystal structure Condensed Matter Physics Crystallography X-ray crystallography General Materials Science Instrumentation Powder diffraction Monoclinic crystal system Solid solution
Zdroj:	Powder Diffraction. 11:268-275
ISSN:	1945-7413 0885-7156
DOI:	10.1017/s0885715600009222
Popis:	Powder X-ray diffraction was used to investigate the solid solution range of the Bi14SrxCa12−xO33 series in the Bi–Sr–Ca–O system. Solid solution forms over the range 1≤x≤7 in Bi14SrxCa12−xO33. Experimental X-ray reference patterns of selected members with x=1, 3, 5, and 7 have been prepared for the powder diffraction file (PDF). These phases are monoclinic, C2/m, with cell parameter a ranging from 21.473(4) to 21.868(4) Å, b from 4.3564(9) to 4.3898(9) Å, c from 12.753(2) to 12.962(2) Å, β from 102.91(2)° to 102.79(1)°, and V from 1162.9(3) to 1213.5(3) Å3, respectively. These parameters increase monotonically as Ca is continuously replaced by the larger Sr.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9ae465cfbe4273fc9af0453a348e3323 https://doi.org/10.1017/s0885715600009222 Zobrazit plný text záznamu