A Possible Relationship between Deep Earthquakes and the Structural Transition of Submolecular SiO2 Fragments in Rocks of a Subducting Oceanic Slab

Autor: Mikhail I. Kuzmin, V. E. Zakhvataev, R. G. Khlebopros, Svetlana G. Kozlova, A. N. Didenko
Rok vydání: 2019
Předmět:
Zdroj: Russian Geology and Geophysics. 60:241-253
ISSN: 1068-7971
DOI: 10.15372/rgg2019038
Popis: —Quantum-chemical calculations show a tendency of SiO2 molecule to transform from linear to isomeric cyclic (bent) form and back. In the latter case, the energy released during the transition isomeric SiO2 → linear SiO2 is about 240 kJ/mole. This hypothetic structural transition of submolecular SiO2 fragments in mantle minerals is supposed to initiate deep-focus high-energy earthquakes at the upper–lower mantle boundary. It is at this depth (600–670 km) that the subducting oceanic slab is delaminated: Its upper part moves “horizontally” along the upper–lower mantle boundary, while its lower part separated into blocks subsides into the lower mantle and reaches the Dʺ layer to accumulate there.
Databáze: OpenAIRE