Synthetic studies and mechanistic observations in nickel-catalyzed polycyclizations

Autor:	John Montgomery, Jeongbeob Seo
Rok vydání:	1998
Předmět:	Nickel chemistry Stereochemistry Organic Chemistry Drug Discovery chemistry.chemical_element Substrate (chemistry) Ring (chemistry) Biochemistry Medicinal chemistry Cycloaddition Catalysis
Zdroj:	Tetrahedron. 54:1131-1144
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(97)10213-7
Popis:	A series of polyunsaturated enones were investigated in Ni(COD)2 / organozinc - mediated cyclizations. One substrate class underwent an efficient [2+2+2] cycloaddition reaction to generate a tricyclic ring system from a linear precursor. A discussion of probable mechanisms is provided.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9aae73ceb3b5038ee6a14eb787680bba https://doi.org/10.1016/s0040-4020(97)10213-7 Zobrazit plný text záznamu Full Text from ScienceDirect