Bilayer Packing of Amphiphilic Cationic Fullerenes in Crystalline Salts: Models for Self-Assembled Nanostructures

Autor:	Christopher J. Chancellor, Adrienne A. Thorn, Christine M. Beavers, Alan L. Balch, Marilyn M. Olmstead
Rok vydání:	2008
Předmět:	Carbon disulfide Fullerene Nanostructure Chemistry Stereochemistry Bilayer Ethyl iodide Cationic polymerization General Chemistry Condensed Matter Physics Crystallography chemistry.chemical_compound Amphiphile Molecule General Materials Science
Zdroj:	Crystal Growth & Design. 8:976-980
ISSN:	1528-7505 1528-7483
DOI:	10.1021/cg070643r
Popis:	The structures of three crystalline salts—[C60(N(CH2CH2)2NH)+][Rh(CO)2Cl2−]·2CS2, [C60(CH2NH(CH3)CH2)+][Rh(CO)2Cl2−]·CS2, and [C60(CH2N(CH3)(CH2CH3)CH2)+](I−)·CH3CH2I—have been determined. Each packs in a bilayered arrangement such that the cationic heads of the fullerene units and the corresponding anions form distinct polar regions, whereas the fullerene cage and the solvate molecules (carbon disulfide or ethyl iodide) are located in distinct hydrophobic regions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a91f4b92c6f97f598461df36e700788 https://doi.org/10.1021/cg070643r Zobrazit plný text záznamu