New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3, and (C4N3OH7)2·ZnHPO3·H2O

Autor:	Mark L. F. Phillips, Rachel M. Yeates, Tina Maria Nenoff, William T. A. Harrison
Rok vydání:	2003
Předmět:	Inorganic Chemistry Crystallography Chemistry Stereochemistry Crystal data Hydrothermal synthesis chemistry.chemical_element Zinc Crystal structure Physical and Theoretical Chemistry Triclinic crystal system Monoclinic crystal system
Zdroj:	Inorganic Chemistry. 42:1493-1498
ISSN:	1520-510X 0020-1669
Popis:	The syntheses, crystal structures, and properties of C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3, and (C4N3OH7)2·ZnHPO3·H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating “terminal” (nonnetworking) Zn−N and Zn−OH2 moieties into zinc centers. Crystal data: C4N3OH7·ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) A, b = 9.5011(4) A, c = 9.9806(4) A, α = 87.451(1)°, β = 85.686(1)°, γ = 89.551(1)°, Z = 4; C4N3OH7·Zn(H2O)HPO3, monoclinic, P21/c (No. 14), a = 10.1198(7) A, b = 7.2996(5) A, c = 13.7421(9) A, β = 107.522(1)°, Z = 4; (C4N3OH7)2·ZnHPO3·H2O, triclinic, P1 (No. 2), a = 10.7289(6) A, b = 10.9051(6)A, c = 13.9881(8) A, α = 89.508(1)°, β = 74.995(1)°, γ = 74.932(1)°, Z = 4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a87c49147f5d5dbd786eea216d9f3dc https://doi.org/10.1021/ic020593+ Zobrazit plný text záznamu