State of the rare earth elements tetapyrazinoporphyrazinate complexes in protic media

Autor:	Olga G. Khelevina, V. P. Kulinich, E. A. Kokareva, N. G. Nikitina
Rok vydání:	2010
Předmět:	Erbium Reaction mechanism Chemistry Inorganic chemistry Rare earth Polymer chemistry chemistry.chemical_element General Chemistry Dissociation (chemistry) Lutetium
Zdroj:	Russian Journal of General Chemistry. 80:1876-1881
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363210090276
Popis:	The acid-base interactions of tetrapyrazinoporphyrazine erbium(III) and lutetium(III) complexes in the media based on acetic and trifluoroacetic acids were investigated. The quantitative characteristics of equilibria between the acid-base forms were revealed. The structure of the acid forms was suggested. The reaction of solvoprotolytic dissociation of the octaphenyltetrapyrazinoporphyrazine lutetium(III) complex in CH3COOH-H2SO4 medium was studied and a scheme of the reaction mechanism was proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a7a29528f71814091f574b15bcf0a86 https://doi.org/10.1134/s1070363210090276 Zobrazit plný text záznamu Plný text ve formátu PDF