Interaction of hydroperoxopalladium complexes, (TpR)(py)Pd–OOH, with hydroxo-nickel and -cobalt complexes, [(μ-OH)(MTpR′)]2(M = Ni, Co), leading to oxidative dehydrogenation of the saturated hydrocarbyl moiety in the ancillary ligand (TpiPr2)

Autor:	Shiro Hikichi, Munetaka Akita, Masato Kujime
Rok vydání:	2003
Předmět:	Inorganic Chemistry Nickel chemistry Ligand chemistry.chemical_element Moiety Dehydrogenation Oxidative phosphorylation Photochemistry Medicinal chemistry Cobalt Isopropyl
Zdroj:	Dalton Trans.. :3506-3515
ISSN:	1477-9234 1477-9226
Popis:	Treatment of hydroperoxopalladium complexes, (TpR)(py)Pd–OOH, with hydroxonickel complexes, [(μ-OH)NiTpR′]2, when either TpR or TpR′ is TpiPr2, results in dehydrogenation of an isopropyl group of the TpiPr2 ligand to give heterobimetallic di-μ-hydroxo complexes bearing the 3-isopropenyl-substituted Tp ligand [HB(pziPr2)2(pz3-isopropenyl-5-iPr). Similar dehydrogenation is observed for the reaction with the hydroxocobalt complex bearing the TpiPr2 ligand. The dehydrogenated products are characterized by spectroscopic and crystallographic methods and a mechanism involving a heterobimetallic μ-peroxo intermediate formed via dehydrative condensation has been proposed for the oxidative dehydrogenation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a6ea4e36f9be4779c3a52dee94fe4e6 https://doi.org/10.1039/b307262m Zobrazit plný text záznamu