Deposition of SiC/Si coatings in a microwave plasma-assisted spouted bed reactor
| Autor: | I.J. van der Walt, Philippus L. Crouse, H. Bissett, J.H. van Laar, J.C. Barry |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
010302 applied physics
Argon Materials science chemistry.chemical_element 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Methyltrichlorosilane chemistry.chemical_compound Crystallinity chemistry Chemical engineering 0103 physical sciences Materials Chemistry Ceramics and Composites Silicon carbide Deposition (phase transition) Graphite Gas composition Particle size 0210 nano-technology |
| Zdroj: | Journal of the European Ceramic Society. 38:1197-1209 |
| ISSN: | 0955-2219 |
| DOI: | 10.1016/j.jeurceramsoc.2017.10.030 |
| Popis: | Silicon carbide (SiC) layers were deposited onto alumina particles in a microwave plasma-assisted spouted bed reactor using methyltrichlorosilane (MTS) and hydrogen mixtures, in argon, as precursor gas feed. The operating parameters studied were enthalpy, gas composition, and pressure. Microwaves were guided from a generator, operating at 2.45 GHz, along a rectangular waveguide intersecting a quartz tube, acting as the reaction zone. A graphite nozzle at the bottom of the tube facilitated the spouting action. Growth rates varied from 50 to 140 μm/h. Overall results indicate that the optimal region for SiC deposition requires relatively high enthalpy (∼5 MJ/kg) and pressure (>−60 kPa) conditions, with hydrogen-to-MTS ratios ∼5:1. The quality (i.e. crystallinity, particle size, Si/C ratios) of the layers improve at these conditions, at the cost of decreased deposition rates. Characterisation was done by XRD, FTIR, XPS, SEM, TEM and EDX, which assisted in developing colour and morphological charts to indicate the changes as a function of changing operating parameters. A microwave plasma spouted bed reactor is demonstrated to be a viable alternative technique for SiC layer deposition onto microspheres. |
| Databáze: | OpenAIRE |
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