Kinetics of the reduction of alkyl halides by a chromium(II) macrocycle

Autor:	Andreja Bakac, Matko Orhanovic, James H. Espenson, Vjera Butković
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Reaction mechanism Chemistry Stereochemistry Kinetics Halide chemistry.chemical_element Chemical reaction Medicinal chemistry Inorganic Chemistry Chemical kinetics Chromium Reaction rate constant Physical and Theoretical Chemistry Alkyl
Zdroj:	Inorganic Chemistry. 32:5886-5888
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00077a038
Popis:	The reduction of alkyl halides is a subject that has been of mechanistic interest for over two decades. Much effort has been expanded in distinguishing among electron-transfer, atom-transfer, and oxidative-addition mechanisms. With the new (H[sub 2]O)[sub 2]CrL[sup 2+] species available, the authors have returned to a reaction type that has been considered before.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a2c633fb10c3d3219b437d88a13a6bf https://doi.org/10.1021/ic00077a038 Zobrazit plný text záznamu