Vapour–liquid equilibria, azeotropic data, excess enthalpies, activity coefficients at infinite dilution and solid–liquid equilibria for binary alcohol–ketone systems

Autor:	Rima Abbas, Jürgen Gmehling
Rok vydání:	2008
Předmět:	Activity coefficient Equation of state Chemistry General Chemical Engineering Azeotrope Enthalpy General Physics and Astronomy VTPR Thermodynamics Physical and Theoretical Chemistry Group contribution method UNIFAC Dilution
Zdroj:	Fluid Phase Equilibria. 267:119-126
ISSN:	0378-3812
DOI:	10.1016/j.fluid.2008.02.021
Popis:	Isothermal vapour–liquid equilibria (VLE), solid–liquid equilibria and excess enthalpies have been measured for the systems cyclohexanone + cyclohexanol and 2-octanone + 1-hexanol. Additionally in this paper binary azeotropic data at different pressures for 1-pentanol + 2-heptanone and 1-hexanol + 2-octanone have been determined with the help of a wire band column. Furthermore activity coefficients at infinite dilution for methanol, ethanol, 1-butanol and 1-propanol in 2-octanone at different temperatures have been measured with the help of the dilutor technique. These data together with literature data for alcohol–ketone systems were used to fit temperature-dependent group interaction parameters for the group contribution method modified UNIFAC (Dortmund) and the group contribution equation of state VTPR.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a17aefd75b9be044b2e72b1edd0c165 https://doi.org/10.1016/j.fluid.2008.02.021 Zobrazit plný text záznamu Full Text from ScienceDirect