Polarographic oxidation of some 5,10-dihydrophenazine derivatives

Autor:	I. A. Yarysheva, I. N. Borukhova, Z. V. Pushkareva, V. F. Gryazev
Rok vydání:	1976
Předmět:	Esr spectra Polarography Chemistry Radical Aqueous acetone Organic Chemistry Inorganic chemistry Anode oxidation
Zdroj:	Chemistry of Heterocyclic Compounds. 12:458-461
ISSN:	1573-8353 0009-3122
Popis:	The polarographic anode oxidation of 5-substituted dihydrophenazines in an aprotic medium and an aqueous acetone solution has one-electron or two-electron character. It was shown by means of the electronic and ESR spectra that the intermediates in the anode oxidation of dihydrophenazine and 5-methyldihydrophenazine are cation radicals and that the products of one-electron oxidation of 1,3-dinitro-5-aryl-substituted dihydrophenazines are phenazyl radicals. The final products of anode oxidation are phenazinium salts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a15b956b32c2c2c15036b7aec29d9a6 https://doi.org/10.1007/bf00480440 Zobrazit plný text záznamu Full text from SpringerLink