Specific features of the reaction of vanadyl acetylacetonate with tert-butyl hydroperoxide

Autor:	M. V. Gulenova, L. P. Stepovik
Rok vydání:	2009
Předmět:	Ligand chemistry.chemical_element General Chemistry Photochemistry Medicinal chemistry Oxygen Acetic acid chemistry.chemical_compound chemistry tert-Butyl hydroperoxide Liberation Singlet state Vanadyl acetylacetonate Benzene
Zdroj:	Russian Journal of General Chemistry. 79:1663-1670
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363209080143
Popis:	Reaction of vanadyl acetylacetonate with tert-butyl hydroperoxide (benzene, 20°C) at any molar ratio leads to the elimination of ligand and its oxidation mainly to CO2 and acetic acid. At the (acac)2VO: t-BuOOH ratio above 1:10 liberation of oxygen partially in the singlet state takes place.
Databáze:	OpenAIRE
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