H 2 mbpdc-funcationalized Cd II 6 cage captures protonated water clusters: Chloride-templated assembly and applications in recognition and separation
| Autor: | Guohui Kang, Shao-Bin Miao, Bao-Ming Ji, Honghong Lan, Dong-Sheng Deng, Chunying Xu |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Chemistry Stereochemistry Cationic polymerization Halide Protonation 010402 general chemistry 01 natural sciences Chloride Hydrothermal circulation 0104 chemical sciences Ion Inorganic Chemistry Polymer chemistry Materials Chemistry medicine Water cluster Physical and Theoretical Chemistry Cage medicine.drug |
| Zdroj: | Inorganic Chemistry Communications. 81:15-17 |
| ISSN: | 1387-7003 |
| Popis: | Assembly of CdCl2 and 3,3′-dimethoxy-2,2′-bipyridine-6,6′-dicarboxylic acid (H2mbpdc) under hydrothermal condition affords a chloride-centered discrete CdII6 cage [Cd6(mbpdc)6Cl]·[H(H2O)14.5] (1), in which a cationic water cluster H+(H2O)10 is present. Our anion-templated assembly system exhibits exclusive encapsulation of Cl− ion, and thus displays potentially applications in the separation of Cl− ion with other halide ions. |
| Databáze: | OpenAIRE |
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