Semicarbazide-based naphthalimide as a highly selective and sensitive colorimetric and 'turn-on' fluorescent chemodosimeter for Cu2+
| Autor: | Yue-Ting Su, Xiao-Xing Fan, Xiao-Xiao Hu, Xin-Qi Zhan, Hong Zheng, Xiao-Lan Zheng |
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| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
Semicarbazide Fluorophore 010405 organic chemistry Metals and Alloys Buffer solution 010402 general chemistry Condensed Matter Physics Photochemistry 01 natural sciences Fluorescence 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound Hydrolysis chemistry visual_art Materials Chemistry visual_art.visual_art_medium Moiety Electrical and Electronic Engineering Selectivity Instrumentation |
| Zdroj: | Sensors and Actuators B: Chemical. 227:191-197 |
| ISSN: | 0925-4005 |
| DOI: | 10.1016/j.snb.2015.12.037 |
| Popis: | A semicarbazide-based naphthalimide was designed and synthesized as a colorimetric fluorescent probe. Upon reaction with Cu2+ in a buffer solution of pH 7.4 (buffer water/acetonitrile = 80:20, v/v), the probe exhibits color changes from colorless to jade-green accompanying remarkable enhancement in its fluorescence, which could be mechanistically ascribed to the Cu2+-promoted hydrolysis of the semicarbazide moiety leading to the release of the green fluorescent 4-amino-1,8-naphthalimide fluorophore. The probe also displayed excellent performance in high sensitivity as well as good selectivity for Cu2+ over other metallic cations. |
| Databáze: | OpenAIRE |
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