Reactions of positive ions with ClN3 at 300K

Autor:	Keith Freel, Nicole Eyet, A. A. Viggiano, Michael C. Heaven
Rok vydání:	2011
Předmět:	Inorganic chemistry Kinetics Analytical chemistry Condensed Matter Physics Ion Reaction coordinate Reaction rate chemistry.chemical_compound Reaction rate constant chemistry Proton affinity Physical and Theoretical Chemistry Ionization energy Instrumentation Spectroscopy Chlorine azide
Zdroj:	International Journal of Mass Spectrometry. 303:220-224
ISSN:	1387-3806
DOI:	10.1016/j.ijms.2011.02.004
Popis:	The kinetics of eighteen positive ions with chlorine azide (ClN3) have been studied using a selected ion flow tube (SIFT). These measurements allowed for the estimation of both the ionization energy, >930 kJ mol−1 (>9.6 eV), and the proton affinity, 713 ± 41 kJ mol−1, of chlorine azide. Reaction rate constants have been determined. Product ions have been identified, and quantified when synthetic complications allowed. In addition, general reaction trends have been observed. A reaction coordinate diagram for the novel reaction of N+ with ClN3 is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::99b34e17341c58fb2c7f9dbde3d1336d https://doi.org/10.1016/j.ijms.2011.02.004 Zobrazit plný text záznamu Full Text from ScienceDirect