Character of reactivity of nitrogen chlorodifluoride

Autor:	K. V. Frosina, V. S. Lapik, Yu. M. Kosyrev, A. V. Fokin, V. F. Bagryantsev
Rok vydání:	1973
Předmět:	Substitution reaction Radical Inorganic chemistry Cyclohexene chemistry.chemical_element General Chemistry Photochemistry Nitrogen chemistry.chemical_compound chemistry Vinylacetylene Reagent SN2 reaction Reactivity (chemistry)
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:1493-1496
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00930046
Popis:	1. A study was made of the reaction of nitrogen chlorodifluoride with the potassium salt of nitroform, cyclohexene, and vinylacetylene, at room temperature and atmospheric pressure. 2. It Is postulated that nitrogen chlorodifluoride is a molecular electrophilic reagent, which enters into substitution reactions by the SN2 mechanism, and can be cleaved during reaction into either ions or radicals, depending on the nature of the partner and the conditions.
Databáze:	OpenAIRE
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