Flash vacuum pyrolysis (FVP) on zeolites: Pyrolysis of 5-β (hydroxyethyl)-5H-dibenzo[a,d]cycloheptene

Autor:	Mircea D. Banciu, Constantin Draghici, Ovidiu Cira, Anca Banciu, Aurica Petride
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Reaction mechanism Fuel Technology Flash vacuum pyrolysis chemistry Organic chemistry Cycloheptene Alcohol Fluorene Pyrolysis Argon atmosphere Analytical Chemistry
Zdroj:	Journal of Analytical and Applied Pyrolysis. 42:177-188
ISSN:	0165-2370
DOI:	10.1016/s0165-2370(97)00037-5
Popis:	FVP of the title alcohol (9) at 0.65 mbar in argon atmosphere at 350 °C in the presence of seven different acidic zeolites afforded 7H-benzo[c]fluorene (13) and 6,11b-dihydro-7H-ben-zo [c]fluorene (12) as main reaction products. The suggested carbocationic reaction mechanism is supported by: 1. (a) the occurrence of two isomeric dibenzo(C9H10)hydrocarbons, namely 1,1a,6,10b-tetrahydro-1,6-methanodibenzo[a,e]cyclopropa[c]cycloheptene (6) and 9,10-dihydro-9,10-propenoanthracene (5), in the pyrolyses of 9 and 2. (b) by the results of FVP of authentic samples of 6 (conducting mainly to hydrocarbons 12 and 13), respectively 5 (affording to greatest extent the minor products observed in pyrolyses of 9).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::99968dc0910b1831ae1766b239b7da7b https://doi.org/10.1016/s0165-2370(97)00037-5 Zobrazit plný text záznamu Full Text from ScienceDirect