Synthesis and study of 2-alkoxy(2-alkylsulfanyl)-4,6-distyrylpyrimidines containing a terminal carbazole group

Autor:	Ekaterina A. Komissarova, Elena V. Shklyaeva, Igor V. Lunegov, Georgii G. Abashev
Rok vydání:	2016
Předmět:	010405 organic chemistry Carbazole Band gap Organic Chemistry Conductivity 010402 general chemistry Ring (chemistry) Electrochemistry Photochemistry 01 natural sciences 0104 chemical sciences Crystallography chemistry.chemical_compound chemistry Alkoxy group Moiety Derivative (chemistry)
Zdroj:	Chemistry of Heterocyclic Compounds. 52:257-261
ISSN:	1573-8353 0009-3122
Popis:	We report the synthesis of new 4,6-distyrylpyrimidines containing an unsubstituted carbazole ring linked with the pyrimidine moiety by a flexible aliphatic seven-membered –O(CH2)6– or –S(CH2)6– bridge. The electrochemical and spectral properties of the synthesized compounds were studied; optical band gaps were calculated from the relevant UV absorption onsets and were found to be equal to 2.55 and 2.54 eV, respectively. A thin film based on the derivative with sulfur-containing bridge (–S(CH2)6–) was deposited on a conductive material and demonstrated to have a smooth surface and hole conductivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9992f97a82cf0edba7076c36eaaf8981 https://doi.org/10.1007/s10593-016-1871-1 Zobrazit plný text záznamu Plný text ve formátu PDF