Magnetic Properties of Cobalt(II) and Nickel(II) Benzoate Adducts with Quinoline Analogues
| Autor: | Shuji Emori, Chiemi Shima |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
inorganic chemicals
Chemistry Quinoline Inorganic chemistry Infrared spectroscopy chemistry.chemical_element General Chemistry Magnetic susceptibility Metal chemistry.chemical_compound Nickel Quinoxaline visual_art Polymer chemistry otorhinolaryngologic diseases visual_art.visual_art_medium Carboxylate Cobalt |
| Zdroj: | Bulletin of the Chemical Society of Japan. 65:1982-1984 |
| ISSN: | 1348-0634 0009-2673 |
| DOI: | 10.1246/bcsj.65.1982 |
| Popis: | Various cobalt(II) and nickel(II) 3-substituted benzoate adducts with quinoline, 4-methylquinoline, and quinoxaline were prepared. They were then characterized by means of magnetic susceptibility and IR spectroscopy. The variation in their magnetic moments is discussed in terms of the basicities of the benzoate ligands as well as the coordinate-bond lengths between the benzoate oxygen and metal atoms. For the nickel(II) compounds, the formation of weak nickel(II)–nickel(II) bonding is suggested. |
| Databáze: | OpenAIRE |
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