Molecular hybrids formed by oxalate bridged dinuclear anions and organometallic cations
Autor: | J. Sala Pala, Carlos J. Gómez-García, F. Bérézovsky, Eugenio Coronado, José Ramón Galán-Mascarós, Smail Triki |
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Rok vydání: | 1999 |
Předmět: |
Magnetic measurements
Stereochemistry Chemistry Mechanical Engineering Metals and Alloys Infrared spectroscopy chemistry.chemical_element Crystal structure Condensed Matter Physics Magnetic susceptibility Oxalate Electronic Optical and Magnetic Materials Crystallography Chromium chemistry.chemical_compound Mechanics of Materials Materials Chemistry Molecule |
Zdroj: | Synthetic Metals. 102:1753-1754 |
ISSN: | 0379-6779 |
DOI: | 10.1016/s0379-6779(98)00402-0 |
Popis: | The syntheses, magnetic properties and infrared spectra of a new series of molecular hybrids formed by association of two magnetic sublattices: (i) oxalate bridged dinuclear anions [V 2 O 2 (ox)(NCS) 6 ] 4− and [M′M′'(ox)(NCS) 8 ] 4 ( M′= Fe III , Cr III ; M′' - Fe III , Cr III ; ox 2 = C 2 O 4 2 and (ii) decamethylferrocenium organometallic cation are presented. The crystal structure of [Fe(Cp * ) 2 ][(C 2 H 5 ) 4 N] 2 [V 2 O 2 (ox)(NCS) 6 ] is also discussed. |
Databáze: | OpenAIRE |
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