Molecular hybrids formed by oxalate bridged dinuclear anions and organometallic cations

Autor: J. Sala Pala, Carlos J. Gómez-García, F. Bérézovsky, Eugenio Coronado, José Ramón Galán-Mascarós, Smail Triki
Rok vydání: 1999
Předmět:
Zdroj: Synthetic Metals. 102:1753-1754
ISSN: 0379-6779
DOI: 10.1016/s0379-6779(98)00402-0
Popis: The syntheses, magnetic properties and infrared spectra of a new series of molecular hybrids formed by association of two magnetic sublattices: (i) oxalate bridged dinuclear anions [V 2 O 2 (ox)(NCS) 6 ] 4− and [M′M′'(ox)(NCS) 8 ] 4 ( M′= Fe III , Cr III ; M′' - Fe III , Cr III ; ox 2 = C 2 O 4 2 and (ii) decamethylferrocenium organometallic cation are presented. The crystal structure of [Fe(Cp * ) 2 ][(C 2 H 5 ) 4 N] 2 [V 2 O 2 (ox)(NCS) 6 ] is also discussed.
Databáze: OpenAIRE