Nickel-Catalyzed Desulfitative C-C Cross Coupling: The Synthesis of 6-Aza-Tetrahydroquinazolines and their Solvatochromism
| Autor: | Gandhi Sivaraman, Arockiam Jesin Beneto, Shanmugam Muthusubramanian, Arumugam Mariappan, Kandasamy Rajaguru, Nattamai Bhuvanesh, Ayyanar Siva |
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| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Solvatochromism chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Catalysis Coupling (electronics) Nickel chemistry Organic chemistry Nickel catalyst Absorption (chemistry) |
| Zdroj: | ChemistrySelect. 1:1729-1736 |
| ISSN: | 2365-6549 |
| DOI: | 10.1002/slct.201600361 |
| Popis: | A convenient nickel catalyzed approach towards the synthesis of diversely substituted 6-aza-tetrahydroquinazolines from pyrido-pyrimidine-2-thione motifs with organo boronic acids by non-basic desulfitative C−C cross coupling strategy is described. The absorption and emission spectral studies on some of the synthesised compounds reveal the existent of D-π-A−D systems displaying solvatochromism. |
| Databáze: | OpenAIRE |
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