ChemInform Abstract: Competitive Pathways via Nonadiabatic Transitions in Photodissociation

Autor:	Hanna Reisler, Lin Feng, Andrei Sanov, David E. Conroy, Victor Aristov
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Chemistry Radical Photodissociation Molecule Hydroxymethyl General Medicine Photochemistry Spectroscopy Isocyanic acid Potential energy Dissociation (chemistry)
Zdroj:	ChemInform. 32
ISSN:	1522-2667 0931-7597
Popis:	Photodissociation processes of molecules and radicals involving multiple pathways and nonadiabatic crossings are studied using the photofragment imaging technique and the core-sampling version of time-of-flight spectroscopy. Capabilities and challenges are illustrated by two systems. The isocyanic acid system demonstrates how interactions among potential energy surfaces can change during dissociation. The hydroxymethyl photodecomposition system highlights Rydberg-valence interactions common in free radicals. The cross-fertilization between theory and experiment is emphasized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::993d2601a480a291d8bae04874148bd8 https://doi.org/10.1002/chin.200144290 Zobrazit plný text záznamu Plný text