Poly (Isonicotinic Acid N-Oxide–Isonicotinate-N-Oxide-Chloro-Uranyl): The Interpenetrating Grids Created by Coordination and Hydrogen Bonds

Autor:	G. Meinrath, Zbigniew Glatty, Maciej Kubicki, Stefan Lis
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Crystallography Pentagonal bipyramidal molecular geometry chemistry Octahedron Hydrogen bond Coordination polymer Oxide General Chemistry Condensed Matter Physics Uranyl Isonicotinic acid Organometallic chemistry
Zdroj:	Journal of Chemical Crystallography. 40:646-649
ISSN:	1572-8854 1074-1542
DOI:	10.1007/s10870-010-9711-0
Popis:	The building blocks of the title compound, [UO2 2+·Cl−·(C6H4NO3)− · (C6H5NO3)]n–uranyl fragment, chloride ion, one deprotonated isonicotinate N-oxide and one isonicotinic acid N-oxide, are arranged in the complicated three dimensional network by means of both coordination and hydrogen bonds. The uranium ion is seven-coordinated, in the fashion intermediate between the pentagonal bipyramid and capped octahedron. The coordination one-dimensional polymer chains are connected by strong carboxyl—carboxyl hydrogen bonds into two dimensional grids. These grids interpenetrate each other like the chain-links. The coordination one-dimensional polymer chains are connected by strong carboxyl—carboxyl hydrogen bonds into two dimensional grids, which interpenetrate each other like the chain-links.
Databáze:	OpenAIRE
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