ChemInform Abstract: Studies Toward Funiculosin. Intramolecular Carbonyl Condensations Using Carboxamidimidazolide Intermediates

Autor: David R. Williams, Yu-Gui Gu, Patrick D. Lowder
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 28
ISSN: 0931-7597
DOI: 10.1002/chin.199720210
Popis: Internal enolate condensations, utilizing carboxamidimidazoles as activated ureas, provide a general synthesis of the 3,5-disubstituted-4-hydroxy-2-pyridinone 2 as found in funiculosin. The novel all-syn-cyclitol, C-liniked to the heterocyclic system, is prepared from croconic acid.
Databáze: OpenAIRE