Redox equilibria of the nitrosonium cation and of its nonbonded complexes

Autor:	Jay K. Kochi, K. Y. Lee, D. J. Kuchynka
Rok vydání:	1990
Předmět:	Nitronium tetrafluoroborate Nitromethane Nitrosonium Inorganic chemistry Photochemistry Redox Inorganic Chemistry Solvent chemistry.chemical_compound Electron transfer chemistry Physical and Theoretical Chemistry Cyclic voltammetry Acetonitrile
Zdroj:	Inorganic Chemistry. 29:4196-4204
ISSN:	1520-510X 0020-1669
Popis:	The coordinatively unsaturated nitrosonium cation is reduced at the reversible redox potential, as determined by the cyclic voltammetry of either the salt NO + BF 4 − on the initial negative scan or nitric oxide on the initial positive scan in acetonitrile. The marked solvent dependence of E° in other aprotic media (such as dichloromethane and nitromethane) correlates linearly with Gutmann's DN parameter for solvent donicity
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::990ff6df2b8f68d0ee3893a0194526c4 https://doi.org/10.1021/ic00346a008 Zobrazit plný text záznamu