Solvothermal synthesis of [Ni(C4H13N3)2]2Sb4S8: the first compound with a cyclic [Sb4S8]4− anion

Autor: Wolfgang Bensch, Ralph Stähler, Christian Näther
Rok vydání: 2001
Předmět:
Zdroj: Chemical Communications. :477-478
ISSN: 1364-548X
1359-7345
DOI: 10.1039/b009583o
Popis: Under mild hydrothermal conditions the novel thioantimonate(III) [Ni(C4H13N3)2]2Sb 4S8 was synthesised using elemental nickel, antimony and sulfur; the structure is composed of cyclic isolated [Sb4S8]4− anions and [Ni(C4H13N3)2]2+ cations.
Databáze: OpenAIRE