Chemoselective and Regiospecific Formylation of 1-Phenyl-1H-pyrazoles Through the Duff Reaction
Autor: | Luciano M. Lião, Francine Pazini, Marcos N. Eberlin, C. H. A. de Oliveira, A. L. de Oliveira, Luiz Carlos da Cunha, V. de Oliveira, Fábio Oliveira, Catarina Viegas, Ricardo Menegatti, J. L. Paz, L. M. Mairink |
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Rok vydání: | 2013 |
Předmět: | |
Zdroj: | Synthetic Communications. 43:1633-1639 |
ISSN: | 1532-2432 0039-7911 |
DOI: | 10.1080/00397911.2012.657764 |
Popis: | The synthesis of formylated 1-phenyl-1H-pyrazole derivatives under the Duff reaction conditions is reported. Our results indicate that 1-phenyl-1H-pyrazole systems containing electron-withdrawing and electron-donating substituents at the phenyl moiety react under the Duff reaction conditions to furnish formylated derivatives in good yields. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file. |
Databáze: | OpenAIRE |
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