Extraction of cobalt-[4-(2-thiazolylazo)resorcinol] complexes

Autor: Lj. Marić, M.J. Herak, Z. Štefanac, M. Široki
Rok vydání: 1981
Předmět:
Zdroj: Journal of Inorganic and Nuclear Chemistry. 43:3357-3361
ISSN: 0022-1902
Popis: The complex species of cobalt formed with 4-(2-thiazolylazo)resorcinol (TAR = H 2 Tar) in aqueous solution at pH 6–8 can be efficiently extracted by tetraphenylarsonium- and tetraphenylphosphonium chloride in chloroform and similar chlorinated solvents. The anionic [Co III Tar 2 ] − species was predominantly extracted, forming an ion-association compound with the cation of the extraction agent. The extracted complexes were studied spectrometrically in solution and by characterization of the isolated solid compounds.
Databáze: OpenAIRE