Thermally Stable Four‐Coordinate Silicon(IV) Complexes with an Si=N Double Bond and an SiN 3 El Skeleton (El = O, S, Se, Te)

Autor:	Reinhold Tacke, Christian Burschka, Anna Ulmer, Johannes A. Baus, Felix M. Mück
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Silicon Double bond Inorganic chemistry Silylene chemistry.chemical_element Crystal structure Sulfur Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Main group element Tellurium Selenium
Zdroj:	European Journal of Inorganic Chemistry. 2015:1860-1864
ISSN:	1099-0682 1434-1948
Popis:	The donor-stabilized silylene 1 reacts with N2O and PhElElPh (El = S, Se, Te) to form the respective silicon(IV) complexes 2–5 with an Si=N double bond. Compounds 2–5 were structurally characterized by crystal structure analyses and NMR spectroscopic studies in the solid state and in solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::98de43e133fda875f4d22b01dd4969b9 https://doi.org/10.1002/ejic.201500083 Zobrazit plný text záznamu Plný text