Syntheses and X-ray crystal structures of [bis{(3,5-dimethylpyrazolyl)3hydridoborato}In]I and [bis{(pyrazolyl)3methylgallato}In][InI4]

Autor:	Mohamed Mazid, Andrew Frazer, Brian Piggott, Michael B. Hursthouse, Mary Harman
Rok vydání:	1992
Předmět:	Chemistry Stereochemistry X-ray chemistry.chemical_element Crystal structure Gallate Pyrazole Inorganic Chemistry Crystallography chemistry.chemical_compound Octahedron X-ray crystallography Materials Chemistry Molecule Physical and Theoretical Chemistry Indium
Zdroj:	Polyhedron. 11:3013-3017
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(00)80169-2
Popis:	The preparation and X-ray crystal structures of [(HB(pz*) 3 ) 2 In]I and [(MeGa(pz) 3 ) 2 In][InI 4 ] (pz = pyrazole, pz* = 3,5-dimethylpyrazole) are described. The cations of these complexes correspond to the unknown indocene cations [η 5 -C 5 R 5 In] + (R = H, Me). The indium centre has fac-fac octahedral coordination from the tridentate ligand. The In—N distances are 2.225–2.273(5) A for the borate and 2.207–2.228(13) A for the gallate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::98d0bf83c96430518c29a5984301aebc https://doi.org/10.1016/s0277-5387(00)80169-2 Zobrazit plný text záznamu