Simultaneous quantification of low Z elements in phosphorus containing alkali borosilicate glass samples by in situ Current normalized external (in air) PIGE method utilizing proton beam from FOTIA
| Autor: | R.K. Mishra, Vishnu Sharma, T.P. Valsala, Amrita Dhara Prakash, C.P. Kaushik, Raghunath Acharya, A. K. Tyagi, P. K. Pujari |
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| Rok vydání: | 2021 |
| Předmět: |
Fabrication
Materials science Borosilicate glass Health Toxicology and Mutagenesis Phosphorus Public Health Environmental and Occupational Health Analytical chemistry chemistry.chemical_element 010403 inorganic & nuclear chemistry Alkali metal 01 natural sciences Pollution 0104 chemical sciences Analytical Chemistry Ion Certified reference materials Nuclear Energy and Engineering chemistry Radiology Nuclear Medicine and imaging Solubility Spectroscopy Beam (structure) |
| Zdroj: | Journal of Radioanalytical and Nuclear Chemistry. 328:519-526 |
| ISSN: | 1588-2780 0236-5731 |
| DOI: | 10.1007/s10967-021-07679-y |
| Popis: | An attempt was made to increase the solubility of High Level liquid Waste (HLW), mainly Cr and Mo, by addition of P2O5 to sodium borosilicate glass. A total of seven different phosphorus containing alkali borosilicate glass samples were in-house fabricated. As a part of chemical quality control, concentrations of four low Z elements namely Si, Na, B and P were determined by in situ current normalized external (in air) Particle Induced Gamma-ray Emission (PIGE) method using low energy proton beam from Folded Tandem Ion Accelerator (FOTIA), BARC. PIGE method was validated by analyzing synthetic elemental standards and suitable certified reference materials. Phosphorus has shown thermal losses during fabrication. |
| Databáze: | OpenAIRE |
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